I take it at the moment your boss is the certifying plumber/drainlayer on your licence. You must have a supervisor according to the Act as licensing works at the moment, so this means if your boss isn't willing to be your supervisor when you go out on your own (and I'm picking he probably won't want to be because you will become competition for him, plus the risk for him with no reward is too great). This means that you need to have a supervisor. Even if you do what you call non permitted work, all it will take is a complaint to the PGDB and you are facing a prosecution for working without supervision. Remember that complaint could come from a customer, your former boss, or anyone else in the plumbing community who knows that you are not a certifier but are working out on your own in competition to them. While this may seem unfair to you, others that have done the time, and passed the exams and are incurring all the costs involved in that i.e. upskilling, maintaining their certifying status, ensuring that the provide supervision to their own staff etc. cannot compete with you in the marketplace when you do not have those costs.
Legally anyone can start a plumbing business, BUT you must have a certifier overseeing you and so without one, you run a huge risk. Only you can judge if that is worth it or not. My advice is to knuckle down and do the study to sit your Certifying exams in plumbing and drainlaying and then once you have served the two years, apply for the status and go out on your own then.
I note you said you had a pretty decent customer base outside of your bosses - remember that if you are perking without your "supervisor" being aware then you can also be prosecuted for that - plus you will have no cover by any sort of public liability insurance. All good until something goes wrong. Speaking of insurance, you would need to check if your customers would be covered if you went out on your own and were not working in accordance with the 2006 Act i.e. without the supervision. Just some food for thought for you.